If nothing's mixed or in a liquid form, I'd think they'd all still be worth a running a test roll. I should think anything mixed would be long worthless.
A bit off track, I tried Caffenol mixes back in 2018-2019, but concluded if I'm going to this trouble, I might as well mix D23 that has fewer ingredients, or something else with up to 4 or so, but more reliable results. For my blood as a non-chemist, the Caffenol process resulted in a strong appreciation for the consistency of known chemicals from defined sources and a slew of experience and expertise involved in their confection. YMMV.
Sadly, while Steve at "Figitalrevolution" produces solid, admirable work using caffenol, the bulk of folks seem more like Lomography's vibe of "if it's bad it must be good" and so tend to associate Caffenol with just bad photography, bad development and/or both. These are NOT the folks using Caffenol on photrio, but what I found a lot examples of back at the time.