Albumen On Glass - Lab Notes & Discussion

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Nomad

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The subject of trying an albumen on glass process arose in the (there was a url link here which no longer exists) thread, but wasn't really proper to it. Rather than allow the original thread to drift further off topic, and possibly cause the process aspect to be missed in searches by subject line, I have started this thread. The plan is for it to serve as a place for documenting my attempts to come up with an albumen on glass process, and for others to comment, discuss, and advise, as things proceed.

My eventual aim, should a viable process be forthcoming, is to make 10x8 glass negatives, using a home-made camera. This size was chosen because it's large enough to make good-sized contact prints, and because 10x8 glass is fairly cheap and readily available in the form of photo clip-frames. While the primary intention is to make negatives, I would also like to try making positives (an albumen-based Ambrotype, in other words).

For the purpose of developing the process, I'll be using smaller clip-frame glass (6x4"), mainly because I already have a makeshift camera to suit this size. The smaller plates are also easier to handle. I believe that a process developed on the smaller plates should be transferrable to the larger ones in terms of chemistry, timings, and the like. Clearly, the physical aspects of handling the plates, quantities of fluids, size of dishes, etc, would need to be scaled up, or methods used that work for both sizes.

Using albumen appeals to me in a few ways. Mainly, it has the potential to be a fairly simple process, insofar as it has the convenience of being dry plate, and avoids the complexities involved with gelatin. The historical literature on albumen plates often mentions the lack of sensitivty (which led to the popularity of wet collodion). While this may be seen as a disadvantage, my subjects of interest are landscapes and architecture rather than portraiture, so relatively high speed isn't a particular requirement. Indeed, the famous Daguerrotype of the street scene devoid of people other than the shoe-shiner and client has a particular appeal, so long exposures of at least several minutes is something I specifically desire. Finally, there is an element of challenge in this because albumen on glass was a short-lived process, having been quickly replaced by wet collodion in the mid 19th century. It would seem that there has been little work done with it since then, so I'm curious to see whether a modern version can be developed. It's almost as if it's a forgotten process which only really got dropped because of the long exposure times.

When albumen on glass was current, several methods were documented. However, there is little in the way of comparison between them, or examples of results from particular methods. Since my knowledge of chemistry and the technicalities of historic photographic processes is rather poor, I'm not in a position to choose any particular method as a starting point. There is also the consideration that some methods used chemicals that would now be considered dangerous, or are very hard for an amateur to obtain. Moreover, some elements of the methods may be simply unnecessary. For instance, a given worker may have used a particular step because it was known to work, but if another worker didn't use that step, or replaced it with another, then there may scope to simplify the process, or at least choose what to do.

Given these, my choice is to proceed from more general principles, using chemicals that one can be happy with in the modern era, working at home. I think the main thing that can be drawn from the variety of historical methods is that they all work (or are claimed to in the literature), which implies that there is no one method that defines 'albumen on glass'. If anything, it could be argued that the process never reached maturity because of it being replaced by wet collodion relatively soon after its introduction. Since the various historical methods are all fundamentally a mixture of a binder and a halogen which is then sensitised, it seems reasonable to suppose that other methods might also work. In short, my initial assumption is that, as long as I start from sensible basics, I should get images; and if I refine the method as needed, I should get better images. The specifics of the method that I end up with are, of course, unknown at present, as is whether that method will bear any similarity to an historical method. If it doesn't, then I will have come up with my own method. If it does, then I will be in a position to relate that method to real images.
 
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Nomad

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A short recap of where things had got to (more details in the Which Halogen? thread).

The solutions used for my initial attempts were...

Albumen Mix
15g albumen powder mixed into 100ml distilled water
4.5g Potassium Iodide (the quantity to make 12ml of 37% solution).
3g Sodium Citrate
3ml rectified spirit
12ml distilled water

Sensitiser
100ml distilled water
10g Silver Nitrate
1 drop of Potassium Dichromate 7% solution (contrast enhancer, apparently)

Developer
2g Gallic Acid
200ml distilled water

The sensitiser was made a few years ago to try making albumen prints, which seemed to work, although I didn't go any further than some very basic attempts on small pieces of paper using a 35mm negative for testing. For subsequent sensitisers, I'll omit the Potassium Dichromate on account of it being rather toxic. (I knew it was nasty when I had made up the original solution, and it had been included on the assumption that film negatives might not have the density range to get good print contrast. Since it doesn't seem to be an essential component for albumen on glass, and given its toxicity, particularly when used at home, it won't be used again.)

In this first attamept, two 6x4 plates were coated and sensitised. One was used with a 5x4 negative to make a contact printed posititve under a UV lamp (5 minutes exposure), and the other to make a negative of an outdoor scene in the makeshift camera (which has a fixed aperture of f/22, exposed for 45 minutes in low UV conditions). Both worked insofar as discernible bits of photographic image appeared on the plates, but there were two issues in particular: the coating was very uneven, and there was some sort of contamination which resulted in blobs or blotches on the plates.

Here's the contact printed positive...

Plate 01 All.jpg


...with some cropping and enhancement...

Plate 01 Crop + Levels.jpg


And the negative image from the camera...

Plate 02 All Neg.jpg


...inverted, cropped and enhanced...

Plate 02 Crop + Levels.jpg


I found that the mixture made using albumen powder was very watery. It whisked into a foam easily enough, but had settled back to a liquid much more quickly than expected - less than an hour. I suspect this may have been a factor in the unevenness of the coating, so have decided to try a new batch using liquid egg white bought in a carton at a local supermarket. This commercial stuff has some guar gum in it, but my reading so far suggests that it shouldn't adversely affect the process (although how well the foam settles back to a liquid is a possible issue).

I have also made a plate dryer using a small 12x10" tray warmer. The add-on parts are made from clear acrylic and consist of a support for the plate (can fit one 10x8 or two 6x4s) which can be levelled, and a cover...

Plate Dryer.jpg


The main reason for this is to try and reduce the amount of dust that lands on the plates, both by covering them, and by reducing the drying time. When I did the first two plates above, I noticed some dust had settled soon after they had been coated (a handful of specks per plate), but that there are rather more blotches in the final images. If these are casued by dust, then the covered dryer should reduce their frequency (which would, in turn, strengthen the inference that they're caused by dust). The cover should also help to create an evenly-distributed warm environmant because it will tend to contain warm air inside.
 
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TheToadMen

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Thanks Nomad.
I'll follow this thread with great interest.
Bert from Holland
 
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Thanks Bert.

Time for an update...

I made up a new batch of albumen mix using the supermarket liquid egg white. 100ml again, all other components the same as before. It whisked up easily enough and this time took a lot longer to settle back to a liquid - there was a hint after an hour, and a bit more at 2 hours. I then went out for a while and found that it had settled at 5 hours. This was poured into a beaker and then strained into a bottle through two layers of muslin wetted with distilled water. I noted that there was about 85ml of liquid, from an original of 100ml albumen and the 15ml of spirit and water.

Holding the two bottles together (this and the mix made with powdered albumen) and giving them various shakes and wiggles, the new batch was noticeably more viscous, although still quite thin (more in line with what I expected based on my earlier albumen print experiment made with real eggs).

For the coating, I initially tried the same method as before - about 0.5 to 1ml of albumen in a pipette, and dropped onto the middle of the plate. It don't flow as readily this time, so I added about the same amount again, and moved it around with a glass stirring rod. At this point, I noticed what appeared to be inclusions, or maybe tiny bubbles. I was able to remove most of these by either pressing with the tip of the rod, or using the rod to move them to the edge of the plate. It occurred to me that they might be remnants of either the Sodium Citrate or Potassium Iodide - when I made up the solution of these before adding to the egg white, there were a few undissolved grains in the beaker. I should have filtered it, but didn't. The inclusions/bubbles I saw during coating looked about the same size, but I couldn't feel anything with the tip of the rod, so I'm not sure what they were. I then coated a second plate and decided to be more generous with the albumen - a full 3ml pipette, and maybe a bit more. Less working with the glass rod this time, and easier to drain the excess off. The result was a much better looking coating - it looked much more even, and there were hardly any inclusions/bubbles.

I then put the plates in my fancy new dryer and went for a break, during which, I found a digital thermometer (the type with a wire thermocouple). I stuck the probe into the warm space, and found that it was rather more warm than I expected at 60-65°C. I also noticed that the plates were looking slightly cloudy. I reckoned I had heated them too much, but decided to continue anyway.

The plates were sensitised as before (in a dish for 2 minutes), washed, and put back into the drier (now adjusted to give about 40°). I then exposed one as a contact print using my 5x4 test negative, which, for those that haven't seen the Which Halogen? thread, produces this image when scanned and inverted...

Test Image - Pos.jpg


Exposure was again 5 minutes under an 11W UV lamp, through a second glass plate to keep the negative flat. The plate was again developed in Gallic Acid for 20 minutes, but this time I agitated it for the full period (previously, I had agitated for a few minutes and then took a break). I also added some intensifier (Aceto-Nitrate of Silver), about 2ml.

The intensifier was...
6g Silver Nitrate
9ml Acetic Acid
100ml Distilled water

The result is a marked improvement over the first effort. Here's plate 3, with only the colour balance adjusted (it's photographed using a cellphone camera on an LED lightbox, and tends to come out blue) and size reduced...

Plate 03 All.jpg


I suspect the big swirly marks are traces of me moving the glass rod around what was probably slightly less liquid than was ideal. Still, a much more even coating, and better density. Unlike the first one, I could see the image form as the development proceeded. There is also a huge improvement in the blotches that the first attempt had. Some of the dark marks are just dark marks, but some, when viewed up close, are similar to those in the first attempts (dark, with a lighter bit in the middle). I'm currently leaning towards the view that they are caused by the inclusions I saw when coating

I had a close look at the coating before sensitising, and the surface reminded me of reticulation of a gelatin negative. Here's a close-up of a part of the above photo showing this...

Plate 03 Detail.jpg


I'm pretty sure this is heat damage.

Overall, I'm very pleased with the result this time - a big improvement.

Here's a summary of the changes in the process...

Replace albumen powder with liquid egg white from the supermarket.
More liquid applied when coating.
Overheated the coated plates in the dryer (dried at ambient previously).
Plates covered while drying.
Constant agitation of the developer (also, the same batch, so older, and now used for a third plate).
Added 2ml of intensifier to developer.

Good progress. Although plate 4 also has the same reticulation-style look to it, I think the coating was better than plate 3. I'll try to get an exposure made on this one soon.
 
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rogeriod

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Hi Nomad,

Two years have passed since this thread was live ... how are you getting on with albumen on glass plates? I'm also interested in this method and am about to have a go. I'm following the attached doc which I have found online a while back.

I've been to Rochester for a workshop on gelatin dry plate photography at GEH but meanwhile I became more interested in albumen glass plates as they require longer exposure times .. so I can get rid of people and passing cars on urbanscapes.

Would be great to hear how you have progressed with your trials!

Best regards

Rogerio
 

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BJC0000

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Almost 8 years ago a contributor calling themselves Nomad posted a series on this subject and briefly got a number of replies.
Since then there doesn't appear to have been any follow-up.
I've recently started to experiment with this process myself and searched all the obvious keywords with no success.
I'd be happy to write up my efforts if anyone's interested but I don't want to cover ground already covered elsewhere.
Any comments anyone?
 

BJC0000

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The reason for wanting a new thread was that after all this time I doubt anyone will see the post and if I was to write a description of my attempts I suspect not many will bother to scroll down to the end of such a log-dead thread
 

koraks

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For brand new information please feel free to open a new thread.
People with an interest in the subject will see this thread or a new one; in practice it doesn't matter much.
 
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